姓名:赵文波
职称:教授 (博士生导师)
研究领域:
1.酸性气体的捕集和利用
2.可变溶剂的分子设计与应用
3.有机碳酸酯与含硫化学品的催化合成
4.金属有机配位聚合物的合成与表征
5.无机多孔化合物的制备与应用
6.有机硅材料的制备与应用
联系方式:wenshuixing@126.com
个人简介:
赵文波,男,1982年生,2009年在中科院煤化所获博士学位,现昆明理工大学教授,博士生导师,云南省首批“兴滇英才支持计划”入选者。主要从事气体捕集与利用,相变溶剂的分子设计以及绿色催化合成方面的科研工作。近年来,主持国家自然科学基金项目4项,省自然科学基金2项,教育部新教师联合基金1项,国家重点实验室开放基金2项,省教育厅重点项目1项,企业横向项目十余项。以第一或通讯作者身份发表论文40余篇,其中一,二区SCI论文十余篇,授权专利十余项。近5年在AIChEJournal,Journal of Hazardous Materials,Separation and Purification Technology,Fuel等顶级期刊上发表论文数篇。
主持研究项目:
[1]面上项目:醇胺捕集二氧化硫热力学上的熵焓互补关系与计算最佳捕集温度的目标函数(编号:22278198),项目负责人
[2]国家基金地区基金:氨烃基硅油体系相变吸收二氧化硫与产物利用(编号:22068016),2021年1月-2024年12月,项目负责人
[3]国家基金地区基金:非水体系相变吸收二氧化硫的机理与吸收剂再生方式研究(编号:21666011),2017年1月-2020年12月,项目负责人
[4]国家基金青年基金:端氨基聚醚的制备及其循环吸收二氧化碳的性能研究(编号:21306071),2014年1月-2016年12月,项目负责人
[5]省厅级项目(昆明理工大学引进人才培养基金):沸石分子筛催化尿素胺解合成六亚甲基二氨基甲酸酯,2010年1月-2013年12月,项目负责人
[6]云南省教育厅科学研究基金重点项目:沸石分子筛催化氨基甲酸甲酯和甲醇合成碳酸二甲酯,2010年1月-2012年12月,项目负责人
[7]省科技厅面上项目:甲基苯基碳酸酯合成中过渡金属离子及其配合物的作用,2014年10月-2017年9月,项目负责人
[8]省部级项目:尿素醇解制备碳酸二甲酯金属离子催化剂的非均相化研究,2011年1月-2013年1月,项目负责人
[9]横项项目:浓硫酸氮氧化物脱除剂的测试加工,2021年4月-2022年1月,项目负责人
[10]横项项目:吸湿盐改性的有机金属框架复合材料开发,2021年7月-2023年7月,项目负责人
主要论文
Wenbo Zhao*,Ling Chen , Qian Zhao , Yuan Chen , Zhiyong Zeng,* Liquid-solid phase-change absorption of SO2 with tertiary diamines in longchain alkane. Separation and Purification Technology 229 (2019) 115814
Shengchao Xu,Wenbo Zhao,*Muyuan Chai, Tian Si, Yuan Chen, and Qingming Jia* Development of SO2 Phase Change Absorption: Viscosity Change and Component Distribution Rules. Energy Fuels 2019, 33, 10, 10029-10038
Zhiyong Xu,Wenbo Zhao,*Xuhao Xie, Yanhong Li, and Yuan Chen Phase-Change Reversible Absorption of Hydrogen Sulfide by the Superbase 1,5-Diazabicyclo[4.3.0]non-5-ene in Organic Solvents Industral & Engineering Chemistry Research, 2019, 58, 1701-1710
Muyuan Chai,Wenbo Zhao*, Genming Li, Shengchao Xu, Qingming Jia, and Yuan Chen. Novel SO2 Phase-Change Absorbent: Mixture of N,N-Dimethylaniline and Liquid Paraffin. Industral & Engineering Chemistry Research, 2018, 57 (37)
Li, Genming;Zhao, Wenbo*; Chai, Muyuan. Liquid-liquid phase-change absorption of SO2 using N, N-dimethylcyclohexylamine as absorbent and liquid paraffin as solvent. Journal of hazardous materials. 2018-Oct-15
Zhao, Qian;Zhao, Wenbo*; Chai, Muyuan. Phase-Change Absorption of SO2 by N,N,N′,N′-Tetramethyl -p-phenylenediamine in Organic Solvents and Utilization of Absorption Product. ENERGY & FUELS. FEB 2018
Zhao, Wenbo*; Zhao, Qian; Zhang, Zheng. Liquid-solid phase-change absorption of acidic gas by polyamine in nonaqueous organic solvent. FUEL. DEC 2017
Wang, Yang; Zhao, Wenbo*; Chai, Muyuan. Phase-Change Absorption of SO2 by Imidazole in Organic Solvents and Conversion of the Absorption Product in the Presence of Water and Oxygen. ENERGY & FUELS. DEC 2017
Zhang, Zheng;Zhao, Wenbo*; Nong, Jiejing. Liquid-Solid Phase-Change Behavior of Diethylenetriamine in Nonaqueous Systems for Carbon Dioxide Absorption. ENERGY TECHNOLOGY MAR 2017
Bing Han,Wenbo Zhao*, Xianye Qin, Yanhong Li, Yanlin Sun, Wei Wei. Synthesis of dimethyl hexane-1,6-diyldicarbamate from 1,6-hexamethylenediamine and methyl carbamate using lead dioxide as catalyst. Catalysis Communications, 2013 Volume 33, Pages 38-41 (SCI)
Yang Jun;Zhao Wen-Bo*; Yang Chao-Fen. Asymmetric Hydrogenation of Acetophenone and Its derivatives Catalyzed by (1S,2S) -DPEN Modified Ir/gamma-Al2O3. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES 2013 Volume 34, Page 1679-1684 (SCI)
Wenbo Zhao*, Ning Zhao, Fukui Xiao, Wei Wei, Sun Yuhan. Macro kinetics study for the synthesis of dimethyl carbonate from urea and methanol on Zn-containing catalyst. Journal of Central South University of Technology, 2012 Volume 19, Number 1, 85-92 (SCI)
Wenbo Zhao*, Yanhong Li, Yanna Liu, Wei Wei. Reaction mechanism and kinetics of dimethyl carbonate synthesis from methyl carbamate and methanol. Industral & Engineering Chemistry Research, 2012 Volume: 51 Issue: 51 Pages: 16580-16589 (SCI)
Zhao, Wenbo*,Liu, Biao,Chen, Jian,Preparation of Amino-Modified PAN Fibers with Triethylenetetramine as Aminating Reagents and Their Application in CO2 Adsorption,Journal of Nanomaterials,2014,2014(940908)(SCI)
Xianye Qin,Wenbo Zhao*,Bing Han,Biao Liu,Peichao Lian,Shuisheng Wu,Synthesis of dimethyl carbonate from methyl carbamate and methanolusing MCM-41 functionalized with sulfonic acid groups as catalyst,Korean Journal of Chemical Engineering, 2015Volume: 32 Issue: 6 Pages: 1064-1068. SCI
Zhao, Wenbo*; Feng, Dong; Nong, Jiejing. Catalysis effect and conversion process of transition metal chlorides in the synthesis of diethyl carbonate from ethyl carbamate and ethanol, REACTION KINETICS MECHANISMS AND CATALYSIS APR 2016
发明专利
1. 一种核壳材料催化剂的制备方法及应用 国内发明(授权) 201510741481.6
2. 一种核壳材料催化剂的制备方法及其应用 国内发明(授权) 201510704209.0
3. 一种通过相变捕集CO2、SO2酸性气体的混合有机溶液 国内发明(授权) 201510675190.1
4. 一种玻璃干燥器 国内实用(授权) 201520078478.6
5. 一种可控水位自动补水的水浴锅 国内实用(授权) 201520078331.7
6. 一种适用于颈口下腹部大的圆底玻璃仪器刷洗的试管刷 国内实用(授权)
7. 一种碳酸二苯酯合成催化剂的制备方法及其应用 国内发明(授权)
8. 一种非均相催化剂的制备方法与应用 国内发明(授权)
9.一种合成碳酸二苯酯的催化剂的制备方法国内发明(授权) 201610770482.8
10.一种便捷气体吸收实验装置国内实用(授权) 201810843931.6
本科生培养
1. 指导本科生李根明等发表SCI一区论文(Li, Genming;Zhao, Wenbo*; Chai, Muyuan. Liquid-liquid phase-change absorption of SO2 using N, N-dimethylcyclohexylamine as absorbent and liquid paraffin as solvent. Journal of hazardous materials. 2018-Oct-15)
2.指导本科生李根明等参加昆明理工大学第四届“互联网+”大学生创新创业大赛获云南省银奖
3.指导本科生卢鹏俊等参加云南省大学生创新创业大赛
研究生培养
自2009年入职昆明理工大学以来,先后指导研究生近30名,始终保持一丝不苟的教学态度,言传身教引导学生成长,教他们本分做人,踏实做事,培养学生的创新思维,掌握科研核心能力。任职期间,目前已有4名学生获得国家级奖学金,4名学生获得省政府奖学金,指导过的学生获得云南省优秀毕业毕业论文、云南省优秀毕业生、昆明理工大学优秀毕业论文、昆明理工大学优秀毕业生等荣誉称号,已毕业的学生有的在广东、四川、辽宁等地继续攻读博士,有的在高校任职,在企事业单位的学生也能胜任相关技术工作。
主讲课程
计算化工应用(本科生)
化工过程分析与合成(本科生)
高等有机化学(研究生)
姓名:李坦
职称:讲师
研究领域:
1.基于DFT模拟光/电催化能源分子转化机制
2.新能源材料设计(锂电池、燃料电池、超级电容器等)
联系方式:li.tan2008@163.com
个人简介:
2012年本科毕业于南京工业大学,2019年博士毕业于太原理工大学,师从樊彩梅教授。2019年至2022年在华南理工大学从事博士后研究工作,合作导师为陈光需教授。2023年1月入职昆明理工大学化学工程学院工作。主要从事光/电催化机理及新能源材料设计的研究工作。截至目前,已在ACS Energy Lett.、Energy Stor. Mater.、ACS NANO、Fuel、Appl. Catal. B等国际学术期刊上发表论文38篇,以一作/共一、通讯发表论文20篇;其中,IF>10期刊论文7篇。
主持研究项目:
[1]碳基能源分子选择性转化位点构筑中电子描述符的开发及应用,云南省基础研究专项-青年项目,5万。
[2]电催化丙烷氧化脱氢在气/固/液三相界面反应器件中的选择性机制研究,第68批中国博士后面上项目,8万。
[3]机器学习助力电催化丙烷脱氢高效选择性活性位点构筑机制的研究,广东省区域联合基金-青年基金项目,10万
[4]昆明理工大学高层次人才引进项目,150万
代表性论文:
1、Biao Zhou, Kezhou Fan, Yanan Chong, Shuang Xu, Jianwu Wei, Jiake Wei, Aleksandr A. Sergeev, Kam Sing Wong,Tan Li*(通讯), Guangxu Chen*, Daiqi Ye*, and Keyou Yan*. Modulating Adsorption–Redox Sites and Charge Separation of Cs3Bi2Br9–x@ AgBr Core–Shell Heterostructure for Selective Toluene Photooxidation[J].ACS Energy Letters, 2024, 9: 1743-1752.(一区Top, IF: 22.0).
2、Qingshuai Xu, Xuejun Lai, Gaige Zhang,Tan Li*(通讯), Yongcai Qiu*. Tailoring the passivation layer on lithium metal anode and aluminum collector by regulating the solvation structure to enhance the long-term cycling of lithium metal batteries[J].Chemical Engineering Journal, 2024, 480: 148021.(一区Top, IF: 15.10).
3、Jinyu Wang, Bo Wang, Zulong Wen, Ning Zhao,Tan Li*(通讯), and Wenbo Zhao*. Adsorption Process Optimization and Adsorbent Evaluation Based on Langmuir Isotherm Model[J].Langmuir, 2023, 39(46): 16404-16414.(二区, IF: 3.90).
4、Yikui Zeng#,Tan Li#(共一), Jinping Zhong, Huiyang Mao, Mingli Fu, Daiqi Ye, Yun Hu*. Unraveling the role of Co3O4facet for photothermal catalytic oxidation of methanol via operando spectroscopy and theoretical investigation.Journal of Colloid and Interface Science, 2023, 643: 360-372.(一区Top, IF: 9.965).
5、Longwen Chen, Feng Liu, Xiaoqian Li, Qiuzhen Tao, Zhaoqin Huang, Qi Zuo, Yanwu Chen*,Tan Li*(通讯), Mingli Fu, Daiqi Ye*. Surface Adsorbed and Lattice Oxygen Activated by the CeO2/Co3O4Interface for Enhancive Catalytic Soot Combustion: Experimental and Theoretical Investigations.Journal of Colloid and Interface Science, 2023, 638: 109-122(一区Top, IF: 9.965).
6、Tan Li#, Qingshuai Xu#, Moaz Waqar, Haitao Yang, Wenbin Gong, Jie Yang*, Jun Zhong*, Zhaolin Liu*. Millisecond-Induced Defect Chemistry Realizes High-Rate Fiber-Shaped Zinc-Ion Battery as A Magnetically Soft Robot.Energy Storage Materials, 2023(55): 64-72(一区Top, IF: 20.831).
7、Peng Wang#,Tan Li#(共一), Qiqi Wu, Ruian Du, Qinghua Zhang, Wei-Hsiang Huang, Chi-Liang Chen, Yan Fan, Haonan Chen, Yanyan Jia, Sheng Dai, Yongcai Qiu, Keyou Yan, Yuanyuan Meng, Geoffrey I. N. Waterhouse, Lin Gu,* Yun Zhao,* Wei-Wei Zhao,* and Guangxu Chen*. Molecular Assembled Electrocatalyst for Highly Selective CO2Fixation to C2+Products.ACS Nano,2022, 16(10): 17021-17032.(一区Top, IF: 18.027).
8、Jie Yang#, Haitao Yang#, Changchun Ye,Tan Li* (通讯), Guangxu Chen, Yongcai Qiu*. Conformal Surface-Nanocoating Strategy to Boost High-Performance Film Cathodes for Flexible Zinc-ion Batteries as An Amphibious Soft Robot.Energy Storage Materials, 2022, 46, 472-481(一区Top, IF: 20.831).
9、Shuaiqi Zhao#,Tan Li# (共一), Jiajin Lin, Peng Wu, Yifei Li, Anqi Li, Tingyu Chen, Yun Zhao, Guangxu Chen, Leneng Yang, Yuanyuan Meng, Xiaojing Jin, Yongcai Qiu*, Daiqi Ye. Engineering Co3+-rich crystal planes on Co3O4hexagonal nanosheets for CO and hydrocarbons oxidation with enhanced catalytic activity and water resistance.Chemical Engineering Journal, 2021, 420: 130448(一区Top, IF: 15.10).
10、Zhenghui Pan#, Lixing Kang#,Tan Li# (共一), Moaz Waqar, Jie Yang*, Qilin Gu, Ximeng Liu, Zongkui Kou, Zhao Wang, Lirong Zheng*, and John Wang*. Black Phosphorus@ Ti3C2TxMXene Composites with Engineered Chemical Bonds for Commercial-Level Capacitive Energy Storage.ACS nano, 2021, 15(8): 12975-12987(一区Top, IF: 18.027).
11、Ruian Du,Tan Li*(通讯), Qiqi Wu, Peng Wang, Xianfeng Yang, Yan Fan, Yongcai Qiu, Keyou Yan, Pei Wang, Yun Zhao*, Wei-Wei Zhao* and Guangxu Chen*. In Situ Engineering the Cu+/Cu0Interface on Oxide-derived Cu Catalyst to Boost C2+Selectivity in CO2Electroreduction.ACS Applied Materials & Interfaces, 2022, 14(32): 36527–36535.(一区Top, IF: 9.5).
12、Tan Li, Xiaochao Zhang*, Changming Zhang, Rui Li, Jianxin Liu, Peide Han, Caimei Fan*. Thermodynamic and kinetic studies on •OH-involved photo-decarboxylation mechanism for waste cooking oils to biofuels.Fuel, 2019, 254: 115665(一区Top, IF: 7.4).
13、Tan Li, Xiaochao Zhang, Changming Zhang, Rui Li, Jianxin Liu, Rui Lv, Hui Zhang, Peide Han, Caimei Fan*, Zhanfeng Zheng. Theoretical insights into photo-induced electron transfer at BiOX (X= F, Cl, Br, I)(001) surfaces and interfaces.Physical Chemistry Chemical Physics, 2019, 21(2): 868-875(二区Top, IF: 3.945).
14、李坦,张小超*,王凯,李瑞,樊彩梅*.α,β,γ,δ,ε,η-Bi2O3电子结构和光学性质的第一性原理研究.高等学校化学学报, 2016, 37(5): 920-927(四区, IF: 0.85).
姓名:徐志勇
职称:讲师
研究领域:
1.基于分子水平的酸性/电子特种气体的捕集
2.蛋白质与材料界面相互作用的研究
联系方式:ZYXu@kust.edu.cn
个人简介:
徐志勇,男,江西抚州人,中共党员,工学博士,硕士生导师。2023年6月博士毕业于华南理工大学,近年来主要从事酸性、电子特种气体的捕集和蛋白质界面相互作用机理的分子模拟研究。以第一/通讯作者在Chemical Engineering Journal, Journal of Hazardous Materials, Separation and Purification Technology, Industrial & Engineering Chemistry Research等国际期刊上发表论文十余篇,同时获得授权中国发明专利2项。曾获本科生国家励志奖学金,研究生国家奖学金,云南省优秀硕士生毕业论文等荣誉。2023年昆明理工大学高层次引进人才。
工作与教育经历:
2023.08-至今 昆明理工大学,化学工程学院,专任教师
2019.09 - 2023.06华南理工大学,化学与化工学院,化学工程与技术,博士
2016.09-2019.06 昆明理工大学,化学工程学院,化学工程,硕士
2012.09-2016.06 西北民族大学,化工学院,化学工程与工艺,学士
主持研究项目:
昆明理工大学高层次人才引进经费,80万元,2023.08-2031.08,在研,主持。
代表性专著与论文:
1. Lurui Wan, Kai Wang, Yuan Chen,Zhiyong Xu*, Wenbo Zhao*. Aminoalkyl organosilicon with dual chemical sites for SO2absorption and analysis of site-specific absorption entropy and enthalpy. Journal of Hazardous Materials,464 (2024) 132946. (一区, TOP期刊, IF: 13.6)
2.Bo Wang, Jinyu Wang, Yuan Chen, Zhiyong Xu*, Wenbo Zhao*. The absorption behavior of SO2 by amine alkyl organosilicon: Experimental and numerical simulation. Chemical Engineering Journal, 2023 (474): 145345. (SCI 一 区TOP)
3.Bo Wang, Jing Chen, Jinyu Wang, Zhiyong Xu*, Wenbo Zhao*. Molecular insights into the absorption of SO2 with amine alkyl organosilicon and its optimal absorption temperature. Separation and Purification Technology, 2024 (340):126660. (SCI 一区 TOP)
4. Wei Zhao, Lurui Wan,Zhiyong Xu*, Xuefei Li, Yang Lan, Wenbo Zhao*, Jing Chen. Aminosiloxane having double absorption sites with low viscosity for efficient SO2capture, Journal of Environmental Chemical Engineering, 11 (2023) 111362. (二区, IF: 7.7)
5.Siyu Hao, Dong Feng*, Feng Wu, Yuhui Xie,Zhiyong Xu*, Wenbo Zhao, Delong Xie. Highly transparent and fire-safe polypropylene carbonate composites via guanidine phosphate hydrogen bonding complexation.Polymer Degradation and Stability, 2023: 110548.(二区, IF: 5.9)
6.Bo Wang, Jinyu Wang, Yuan Chen,Zhiyong Xu*, Wenbo Zhao*.The absorption behavior of SO2by amine alkyl organosilicon: Experimental analysis and numerical simulation. Chemical Engineering Journal, 2023, 474: 145345.(一区, TOP期刊, IF: 15.1)
7.Kai Wang, Guangzhen Li, Yanhong Li, Yuan Chen, Ling Zhang, Zhiying Zhu,Zhiyong Xu*, Wenbo Zhao*.Entropy enthalpy compensation in the SO2absorption reaction and the optimal capture temperature range with amine alkyl siloxane as absorbent. Separation and Purification Technology, 2023, 306: 122581. (一区, TOP期刊, IF: 8.6)
8.Zhiyong Xu, Jian Zhou*. Molecular Insights of Cellobiose Dehydrogenase Adsorption on Self-Assembled Monolayers. Langmuir, 2023, 39(16): 5880-5890.(二区, TOP期刊, IF: 3.9)
9.Zhiyong Xu, Shengjiang Yang, Yun Xie, Hai Yu, Jian Zhou*. Modulating the adsorption orientation of methionine-rich laccase by tailoring the surface chemistry of single-walled carbon nanotubes. Colloids and Surfaces B: Biointerfaces,2022, 217: 112660.(二区, TOP期刊, IF: 5.8)
10.Zhiyong Xu, Zhongjin He, Xuebo Quan, Delin Sun, Zhaohong Miao, Hai Yu, Shengjiang Yang, Zheng Chen, Jinxiang Zeng, Jian Zhou*. Molecular simulations of charged complex fluids: A review. Chinese Journal of Chemical Engineering, 2021, 31: 206-226. (二区,卓越计划梯队期刊, IF: 3.8)
11.Zhiyong Xu,Wenbo Zhao*, Xuhao Xie, Shengchao Xu, Yuan Chen. Liquid-liquid phase-change absorption of hydrogen sulfide by superbase 1,8-diazabicyclo[5.4.0]undec-7-ene and its chemical regeneration. Separation and Purification Technology, 2020, 250: 117244. (一区, TOP期刊, IF: 8.6)
12.Zhiyong Xu, Wenbo Zhao*, Xuhao Xie, Yanhong Li, Yuan Chen. Phase-change reversible absorption of hydrogen sulfide by the superbase 1,5-diazabicyclo [4.3.0] non-5-ene in organic solvents. Industrial & Engineering Chemistry Research,2019, 58(4): 1701-1710.(化工三大刊, IF: 4.2)
代表性专利:
1.赵文波,徐志勇,陈媛,柴牧原,陈玲.一种二氧化碳与有机胺间接合成有机碳酸酯的方法,公开号: CN108586243B.
2.赵文波,徐志勇,冯东,陈媛,李艳红,汪洋,赵倩.一种核壳材料催化剂的制备方法及其应用,公开号: CN106040291B.